Browsing by Author "Morales Torres, Sergio"
Now showing 1 - 2 of 2
- Results Per Page
- Sort Options
Item Enhanced catalytic performance of ZnO/carbon materials in the green synthesis of poly-substituted quinolines.(Journal of Environmental Chemical Engineering, 2022) Godino Ojer, Marina; Morales Torres, Sergio; Pérez Mayoral, Elena; Maldonado Hódar, Francisco J.A highly efficient methodology for the selective synthesis of nitrogen heterocycles via Friedländer reaction using carbon materials supported ZnO catalysts under the green chemistry domain is presented. The influence of the physicochemical properties of different carbon supports, in particular an activated carbon (AC), multi-walled carbon nanotubes (MWCNT) and a carbon aerogel (CA), on the catalytic performance is discussed. The developed catalysts are easily prepared by simple incipient wetness impregnation and a subsequent thermal treatment. These ZnO/carbon catalysts showed a great performance in the Friedländer condensation of 2-amino-5-chlorobenzaldehyde and carbonylic compounds with enolizable hydrogens, under solvent-free and mild conditions, affording in all cases selectively a total conversion to the corresponding quinoline. Both the Zn loading in combination with the developed microporosity of the selected carbon supports seem to be the key factors determining the catalytic performance. Yields obtained with ZnO/carbon composites catalysts are superior to those obtained by others widely used in fine chemistry such as, Zn-catalysts supported on mesoporous silica (SBA-15) and Zn-metal-organic-frameworks (MOF).Item Towards selective synthesis of quinoxalines by using transition metals-doped carbon aerogels.(Catalysis Today, 2023) Godino Ojer, Marina; Morales Torres, Sergio; Maldonado-H´odar; Pérez-Mayoral, E.metal (TM)-carbon aerogels, where TM = Mo, Fe, Co or Cu, were found to be active and selective catalysts for the synthesis of quinoxalines 1, from o-phenylenediamine 2 and α-hydroxy ketones 3, becoming an efficient and sustainable alternative to other carbon-based catalysts or even MOF. Doping metal phase consisting of the corresponding metal oxides but also as zero-valent metals depending on the metal and carbonization temperature, and metal loading at the surface of carbon aerogel are key factors conditioning both reactivity and selectivity. Although metal oxides are probably the predominant active catalytic species, zero-valent metals nanoparticles (Cu0 or Co0) could be implied in the last dehydrogenation step of the reaction. Moreover, the additional functionalization with oxygenated surface groups (Co-1000PO catalyst) resulted on an enhanced reactivity probably due to the cooperation between both functions. Remarkably, Mo- 500 catalyst was the most efficient sample selectively leading to the quinoxaline 1a in high conversion. Finally, our results strongly suggest different operative pathways when using TM-doped carbon aerogels depending on the metallic phase at the carbon surface. While TM-doped carbon aerogels (where TM = Fe, Co, or Cu) probably act catalyzing a sequential acid-base steps and subsequent aromatization leading to the corresponding quinoxaline 1a, Mo-doped catalyst would work via the initial oxidation of α-hydroxy ketones followed by condensation-dehydration reactions.