Chlorination and Solvothermal Treatment of Zr(C5H5)2Cl2: a Synthetic Combination to Produce Nanometric Tetragonal ZrO2.

dc.contributor.authorÁvila Brande, D.
dc.contributor.authorPerezzan, Ramiro
dc.contributor.authorUrones Garrote, E.
dc.contributor.authorOtero Díaz, L.C.
dc.date.accessioned2024-02-06T11:21:40Z
dc.date.available2024-02-06T11:21:40Z
dc.date.issued2011
dc.description.abstractA novel synthetic strategy based on the combination of the chlorination of an organometallic precursor followed by solvothermal treatment is found to be successful in the synthesis of tetragonal nano-ZrO2 or nano-ZrO2, embedded in an amorphous carbon matrix, depending on the solvent employed in the solvothermal step. The chemical and structural features (chemical composition, size and surface defects) of the intermediate and final materials have been determined experimentally mainly by high resolution transmission electron microscopy, electron energy loss spectroscopy, and Z-contrast images. These local techniques reveal that the nanoparticles consist of tetragonal ZrO2 with an average size of 1.7 ± 0.4 and 6.2 ± 0.9 nm for the embedded in carbon and the free nano-ZrO2, respectively.spa
dc.identifier.doi10.1021/ic2004112spa
dc.identifier.issn0020-1669spa
dc.identifier.urihttps://hdl.handle.net/10641/3875
dc.language.isoengspa
dc.publisherInorganic Chemistryspa
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/ic2004112spa
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accessspa
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.titleChlorination and Solvothermal Treatment of Zr(C5H5)2Cl2: a Synthetic Combination to Produce Nanometric Tetragonal ZrO2.spa
dc.typejournal articlespa
dc.type.hasVersionSMURspa
dspace.entity.typePublication
relation.isAuthorOfPublication744ba463-4ba9-49b4-96ea-30a60ab3c364
relation.isAuthorOfPublication.latestForDiscovery744ba463-4ba9-49b4-96ea-30a60ab3c364

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