Basolites: a type of Metal Organic Frameworks highly efficient in the one-pot synthesis of quinoxalines from a-hydroxy ketones under aerobic conditions.
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2019
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Catalysis Today
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Abstract
We report here efficient synthesis of quinoxalines from ophenylendiamine
and -hydroxy ketones over commercial Basolites.
The concentration and type of acid centres, as CUS sites, together
with the porosity of the samples strongly influence the resulting
conversion and selectivity. Our results indicate a new reaction route
in which tautomerization reactions are also involved.
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Basolites, Metal-Organic-Frameworks, Nanocatalysts, Fine chemicals, Quinoxalines